N. Jayaraman
Professor & Chair
Phone : +91-80-2293-2578 (office); 2293-2406 (lab)
E-mail: jayaraman@iisc.ac.in
Home Page : https://njiisc.in/
Biography
Education
M.Sc.: Annamalai University, Chidambaram, 1988
Ph.D.: Indian Institute of Technology, Kanpur (1988 – 1994) (Supervisor: Professor S. Ranganathan)
Postdoctoral Fellow: University of Birmingham, England (1994 – 1997) University of California, Los Angeles, USA (1997 – 1999) (Mentor: Professor Sir J.F. Stoddart)
Research Interests
Major research programs of the group are focused in two areas of organic chemistry and synthesis, namely, carbohydrates and dendrimers.
In carbohydrates, on-going research pertains to:
- Synthesis of natural and un-natural target sugar molecules;
- Synthesis and studies of oligosaccharides and glycolipids;
- Biochemical and biophysical studies of carbohydrate-protein interactions.
In the area of macromolecular dendrimers, the research activities are on:
- Synthesis of poly(ether imine) and poly(alkyl aryl ether) dendrimers;
- Organometallic catalysis using multivalent dendritic catalysts;
- Grafting of dendrons on to one-dimensional polymers and physical studies.
Representative Publications
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Carbohydrate Chemistry
- “Facial Selectivities in the Nucleophilic Additions of 2,3-Unsaturated 3-Arylsulfinyl Pyranosides”, Mukherjee, A.; Jayaraman, N. Carbohydr. Res. 2013, 380, 51 – 58.
- “Glycosidic Bond Hydrolysis in Septanosides: A Comparison of Mono-, Di-, and 2-Chloro-2-Deoxy-Septanosides”, Dey, S.; Jayaraman, N. Carbohydr. Res. 2014, 399, 49 – 56.
- “Backbone-Modified Amphiphilic Cyclic Di- and Tetrasaccharides”, Daskhan, G. C.; Jayaraman, N. Chem. Commun. 2014, 50, 8554 – 8557.
- “Synthetic Arabinomannan Glycolipids Impede Mycobacterial Growth, Sliding Motility and Biofilm Structure”, Syal, K.; Maiti, K. G.; Naresh, K.; Avaji, P. G.; Chatterji, D.; Jayaraman, N. Glycoconjugate J. 2016, 33, 763–777.
- “Synthesis and Structure of Cyclic Trisaccharide with Expanded Glycosidic Linkages”, Maiti, K.; Jayaraman, N. J. Org. Chem. 2016, 81, 4616 – 4622.
- “Chemical and Enzymatic Approaches to the Synthesis of Cyclic Oligosaccharides”, Maiti, K.; Samanta, G. C.; Daskhan, G. C. ; Jayaraman, N. Carbohydr. Chem. 2017, 42, 165–209.
Dendrimer Chemistry
- “Multivalent Dendritic Catalysts in Organometallic Catalysis”, Bagul, R. S.; Jayaraman, N. Inorg. Chim. Acta, 2014, 409, 34–52.
- “Covalent Assembly-Disassembly of Poly(Ether Imine) Dendritic Macromolecular Monomers and Megamers”, Bagul, R. S.; Jayaraman, N. Polymer, 2014, 55, 5102 – 5110.
- “Dendritic Bis- and Tetrakis-Iminodiacetic Acid-Boronate Complexes in One-Pot Cross-Coupling Reactions”, Sharma, A.; Kumar, P.; Pal, R.; Jayaraman, N. J. Orgmet. Chem. 2016, 819, 138 – 146.
- “Multicolor Reversible Thermochromic Properties of Gallic Acid-Cored Polydiacetylenes Appended with Poly(alkyl aryl ether) Dendrons”, Singh, Y.; Jayaraman, N. Macromol. Chem. Phys. 2016, 217, 940 – 950.
- “In-Plane Modulated Smectic ~A vs Smectic ‘A’ Lamellar Structures in Poly(Ethyl or Propyl Ether Imine) Dendrimers”, Kumar, P.; Rao, D. S.S.; Prasad, S. K.; Jayaraman, N. Polymer, 2016, 86, 98 – 104.
- “Visual Detection of pH and Biomolecular Interactions at Micromolar Concentrations Aided by a Trivalent Diacetylene-Based Vesicle” Singh, Y.; Jayaraman, N. Macromol. Chem. Phys. 2017, 1700039, pp. 1-11.
Awards / Honours / Affiliations
- Professor Swaminathan Endowment Lecture, University of Madras, Chennai (2007)
- Chemical Research Society of India medal (2007)
- Diamond Jubilee Fellow of the Institute of Chemical Technology, Mumbai (2008-2009)
- Shanti Swarup Bhatnagar Prize (2009)
- Rajib Goyal Prize (2011)
- Fellow of Indian Academy of Sciences, India (2011)